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Ring-opening polymerizations are generally initiated by the same types of ionic initiators previously described for the cationic and anionic polymerizations of monomers with carbon carbon and carbon oxygen double bonds (Chap. 5). Most cationic ring-opening polymerizations involve the formation and propagation of oxonium ion centers. Reaction

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While ecclesiastical establishments now rarely lent money, the Order of Knights Templar, retiring from the Levant, became a great banking organization The French and Flemish civilizations revived brilliantly French wines began to enjoy a dominant position in trade Flemish cloth, now made of superior English wool (226), became another dominant item of trade Italian, Spanish, German, and English merchants installed factories at Bruges, which was called the Venice of the North It was the point of entry for English wool Bruges later supplanted the Champagne fairs (227) as the meeting place of north and south; it was not periodic like the fairs Philip the Fair of France later helped Bruges by closing the great trade routes through Champagne and ruining the cloth industry of Artois.

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involves the nucleophilic attack of monomer on the oxonium ion:

The typical anionic ring-opening polymerization involves the formation and propagation of anionic centers. Reaction proceeds by nucleophilic attack of the propagating anion on monomer:

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(228) By the close of the thirteenth century the Germans in Bruges had become the chief exporters of Flemish cloth and the principal buyers of Italian imports The German Hanseatic League dominated the trade of northern Europe Cologne was then the leading trading and cultural town of Germany The German trade route led through Hamburg and L beck to the Baltic and Scandinavia and the East At the same time great English merchant families grew up in the city of London, financed the king, and held large investments in land and mortgages The wool trade continued to be dominant in England The currencies of Europe were still in debased confusion In order to provide reliable currency, some superior gold coins were struck by trading cities: the florin in Florence, 1252; the ducat in Venice, 1284 The rentier class continued to expand.